Aramid fibers, short for aromatic polyamide, are a class of heat-resistant and strong

synthetic fiber Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) ...

s. They are used in aerospace and military applications, for ballistic-rated

body armor Body armor, also known as body armour, personal armor or armour, or a suit or coat of armor, is protective clothing designed to absorb or deflect physical attacks. Historically used to protect military personnel, today it is also used by variou ...

fabric Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...

and ballistic composites, in marine cordage, marine hull reinforcement, and as an

asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...

substitute. The chain molecules in the fibers are highly oriented along the fiber axis. As a result, a higher proportion of the

chemical bond A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...

contributes more to fiber strength than in many other synthetic fibers. Aramids have a very high melting point (>500 °C). Common aramid

brand name A brand is a name, term, design, symbol or any other feature that distinguishes one seller's good or service from those of other sellers. Brands are used in business, marketing, and advertising for recognition and, importantly, to create an ...

s include

Kevlar Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, the high-strength material was first used commercially in the early 1970s a ...

Nomex Nomex is a flame-resistant meta-aramid material developed in the early 1960s by DuPont and first marketed in 1967. Properties Nomex and related aramid polymers are related to nylon, but have aromatic backbones, and hence are more rigid and mo ...

, and

Twaron Twaron (a brand name of Teijin Aramid) is a para-aramid. It is a heat-resistant and strong synthetic fibre developed in the early 1970s by the Dutch company Akzo Nobel's division Enka BV, later Akzo Industrial Fibers. The research name of the para ...

Terminology and chemical structure

''Aramid'' is a shortened form of

aromatic In chemistry, aromaticity is a chemical property of cyclic ( ring-shaped), ''typically'' planar (flat) molecular structures with pi bonds in resonance (those containing delocalized electrons) that gives increased stability compared to satur ...

polyamide A polyamide is a polymer with repeating units linked by amide bonds. Polyamides occur both naturally and artificially. Examples of naturally occurring polyamides are proteins, such as wool and silk. Artificially made polyamides can be made through ...

. The term was introduced in 1972, accepted in 1974 by the

Federal Trade Commission The Federal Trade Commission (FTC) is an independent agency of the United States government whose principal mission is the enforcement of civil (non-criminal) antitrust law and the promotion of consumer protection. The FTC shares jurisdiction ov ...

of the USA as the name of a generic category of fiber distinct from

nylon Nylon is a generic designation for a family of synthetic polymers composed of polyamides ( repeating units linked by amide links).The polyamides may be aliphatic or semi-aromatic. Nylon is a silk-like thermoplastic, generally made from petro ...

, and adopted by the

International Standards Organisation The International Organization for Standardization (ISO ) is an international standard development organization composed of representatives from the national standards organizations of member countries. Membership requirements are given in Art ...

in 1977. Aromatic in the name refers to the presence of

aromatic rings In chemistry, aromaticity is a chemical property of cyclic ( ring-shaped), ''typically'' planar (flat) molecular structures with pi bonds in resonance (those containing delocalized electrons) that gives increased stability compared to saturat ...

of six carbon atoms. In aramids these rings are connected via amide linkages each comprising a CO group attached to an NH group. In order to meet the FTC definition of an aramid,Commercial Practices, Part 303,
§303.7 ''Generic names and definitions for manufactured fibers.''
/ref> at least 85% of these linkages must be attached to two aromatic rings.

Para-aramids and meta-aramids

Aramids are divided into two main types according to where the linkages attach to the rings. Numbering the carbon atoms sequentially around a ring, para-aramids have the linkages attached at positions 1 and 4, while meta-aramids have them at positions 1 and 3. That is, the attachment points are diametrically opposite each other in para-aramids, and two atoms apart in meta-aramids. The illustration thus shows a para-aramid.

History

Aromatic polyamides were first introduced in commercial applications in the early 1960s, with a

meta Meta (from the Greek μετά, '' meta'', meaning "after" or "beyond") is a prefix meaning "more comprehensive" or "transcending". In modern nomenclature, ''meta''- can also serve as a prefix meaning self-referential, as a field of study or ende ...

-aramid fiber produced by

DuPont DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in ...

as HT-1 and then under the trade name

. This fiber, which handles similarly to normal textile apparel fibers, is characterized by its excellent resistance to heat, as it neither melts nor ignites in normal levels of oxygen. It is used extensively in the production of protective apparel, air filtration, thermal and electrical insulation, as well as a substitute for

. Meta-aramids are also produced in the Netherlands and Japan by

Teijin Aramid Teijin Aramid, formerly known as Teijin Twaron, is a company in The Netherlands that produces various high-strength fibers for industrial purposes, most notably their para-aramid, Twaron. Twaron finds applications in numerous markets, such as au ...

under the trade name Teijinconex, in Korea by

Toray is a multinational corporation headquartered in Japan that specializes in industrial products centered on technologies in organic synthetic chemistry, polymer chemistry, and biochemistry. Its founding business areas were fibers and textiles, ...

under the trade name Arawin, in China by Yantai Tayho under the trade name New Star and by SRO Group under the trade name X-Fiper, and a variant of meta-aramid in France by Kermel under the trade name Kermel. Based on earlier research by

Monsanto Company The Monsanto Company () was an American agrochemical and agricultural biotechnology corporation founded in 1901 and headquartered in Creve Coeur, Missouri. Monsanto's best known product is Roundup (herbicide), Roundup, a glyphosate-based herbic ...

and

Bayer Bayer AG (, commonly pronounced ; ) is a German multinational corporation, multinational pharmaceutical and biotechnology company and one of the largest pharmaceutical companies in the world. Headquartered in Leverkusen, Bayer's areas of busi ...

para Para, or PARA, may refer to: Businesses and organizations * Paramount Global, traded as PARA on the Nasdaq stock exchange * Para Group, the former name of CT Corp * Para Rubber, now Skellerup, a New Zealand manufacturer * Para USA, formerly ...

-aramid fiber with much higher tenacity and

elastic modulus An elastic modulus (also known as modulus of elasticity) is the unit of measurement of an object's or substance's resistance to being deformed elastically (i.e., non-permanently) when a stress is applied to it. The elastic modulus of an object is ...

was also developed in the 1960s and 1970s by DuPont and

AkzoNobel Akzo Nobel N.V., stylized as AkzoNobel, is a Dutch multinational company which creates paints and performance coatings for both industry and consumers worldwide. Headquartered in Amsterdam, the company has activities in more than 80 countries, ...

, both profiting from their knowledge of

rayon Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose f ...

polyester Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include natural ...

and nylon processing. In 1973 DuPont was the first company to introduce a para-aramid fiber, calling it

; this remains one of the best-known para-aramids and/or aramids. In 1978, Akzo introduced a similar fiber with roughly the same chemical structure calling it

. Due to earlier patents on the production process, Akzo and DuPont engaged in a patent dispute in the 1980s. Twaron subsequently came under the ownership of the Teijin Aramid Company. In 2011, Yantai Tayho introduced similar fiber which is called Taparan in China (see

Production Production may refer to: Economics and business * Production (economics) * Production, the act of manufacturing goods * Production, in the outline of industrial organization, the act of making products (goods and services) * Production as a stati ...

). Para-aramids are used in many high-tech applications, such as aerospace and military applications, for "bullet-proof"

. Both meta-aramid and para-aramid fiber can be used to make aramid paper. Aramid paper is used as electrical insulation materials and construction materials to make honeycomb core. Dupont made aramid paper during the 1960s, calling it Nomex paper. Yantai Metastar Special Paper introduced an aramid paper in 2007, which is called metastar paper. Both Dupont and Yantai Metastar make meta-aramid and para-aramid paper.

Health

During the 1990s, an ''

in vitro ''In vitro'' (meaning in glass, or ''in the glass'') studies are performed with microorganisms, cells, or biological molecules outside their normal biological context. Colloquially called "test-tube experiments", these studies in biology an ...

'' test of aramid fibers showed they exhibited "many of the same effects on

epithelial cell Epithelium or epithelial tissue is one of the four basic types of animal tissue, along with connective tissue, muscle tissue and nervous tissue. It is a thin, continuous, protective layer of compactly packed cells with a little intercellula ...

s as did

, including increased

radiolabel A radioactive tracer, radiotracer, or radioactive label is a chemical compound in which one or more atoms have been replaced by a radionuclide so by virtue of its radioactive decay it can be used to explore the mechanism of chemical reactions by tr ...

nucleotide Nucleotides are organic molecules consisting of a nucleoside and a phosphate. They serve as monomeric units of the nucleic acid polymers – deoxyribonucleic acid (DNA) and ribonucleic acid (RNA), both of which are essential biomolecules wi ...

incorporation into DNA and induction of ODC (

ornithine decarboxylase The enzyme ornithine decarboxylase (, ODC) catalyzes the decarboxylation of ornithine (a product of the urea cycle) to form putrescine. This reaction is the committed step in polyamine synthesis. In humans, this protein has 461 amino acids and fo ...

) enzyme activity", raising the possibility of

carcinogenic A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive substan ...

implications. However, in 2009, it was shown that inhaled aramid fibrils are shortened and quickly cleared from the body and pose little risk. A declaration of interest correction was later provided by the author of the study stating that "This review was commissioned and funded by DuPont and Teijin Aramid, but the author alone was responsible for the content and writing of the paper."

Production

World capacity of para-aramid production was estimated at about 41,000

tonne The tonne ( or ; symbol: t) is a unit of mass equal to 1000 kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...

s per year in 2002 and increases each year by 5–10%. In 2007 this means a total production capacity of around 55,000 tonnes per year.

Polymer preparation

Aramids are generally prepared by the reaction between an

amine In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituen ...

group and a

carboxylic acid In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an R-group. The general formula of a carboxylic acid is or , with R referring to the alkyl, alkenyl, aryl, or other group. Carboxylic ...

halide In chemistry, a halide (rarely halogenide) is a binary chemical compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluor ...

group. Simple AB

homopolymer A polymer (; Greek '' poly-'', "many" + '' -mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic an ...

s have the connectivity −(NH−C₆H₄−CO)_''n''−. Well-known aramid polymers such as

, New Star, and Teijinconex) are prepared from diamine and diacid (or equivalent) precursors. These polymers can be further classified according to the linkages on the aromatic subunits. Nomex, Teijinconex, and New Star contain predominantly the meta-linkage. They are called poly-metaphenylene isophthalamides (MPIAs). By contrast, Kevlar and Twaron both feature para-linkages. They are called ''p''-phenylene terephthalamides (PPTAs). PPTA is a product of ''p''-phenylene diamine (PPD) and terephthaloyl dichloride (TDC or TCl). Production of PPTA relies on a co-solvent with an

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

ic component (

calcium chloride Calcium chloride is an inorganic compound, a salt with the chemical formula . It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with calcium hydroxide. Ca ...

, CaCl₂) to occupy the

hydrogen bond In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a ...

s of the amide groups, and an organic component ( N-methyl pyrrolidone, NMP) to dissolve the

polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...

. This process was invented by Leo Vollbracht at Akzo. Apart from the

hexamethylphosphorous triamide (HMPT), still no practical alternative of dissolving the polymer is known. The use of the NMP/CaCl₂ system led to an extended patent dispute between Akzo and DuPont.

Spinning

After production of the polymer, the aramid fiber is produced by

spinning Spin or spinning most often refers to: * Spinning (textiles), the creation of yarn or thread by twisting fibers together, traditionally by hand spinning * Spin, the rotation of an object around a central axis * Spin (propaganda), an intentionally b ...

the dissolved polymer to a

solid Solid is one of the State of matter#Four fundamental states, four fundamental states of matter (the others being liquid, gas, and Plasma (physics), plasma). The molecules in a solid are closely packed together and contain the least amount o ...

fiber from a

liquid A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, a ...

chemical blend. Polymer solvent for spinning PPTA is generally 100%

anhydrous A substance is anhydrous if it contains no water. Many processes in chemistry can be impeded by the presence of water; therefore, it is important that water-free reagents and techniques are used. In practice, however, it is very difficult to achie ...

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...

(H₂SO₄).

Appearances

Fiber Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate ...

* Chopped fiber *

Powder A powder is a dry, bulk solid composed of many very fine particles that may flow freely when shaken or tilted. Powders are a special sub-class of granular materials, although the terms ''powder'' and ''granular'' are sometimes used to distin ...

Pulp Pulp may refer to: * Pulp (fruit), the inner flesh of fruit Engineering * Dissolving pulp, highly purified cellulose used in fibre and film manufacture * Pulp (paper), the fibrous material used to make paper * Molded pulp, a packaging material ...

Other types of aramids

Besides meta-aramids like Nomex, other variations belong to the aramid fiber range. These are mainly of the copolyamide type, best known under the brand name

Technora Technora is an aramid that is useful for a variety of applications that require high strength or chemical resistance. It is a brand name of the company Teijin Aramid. Technora was used on January 25, 2004 to suspend the NASA Mars rover Opportunit ...

, as developed by Teijin and introduced in 1976. The manufacturing process of Technora reacts PPD and 3,4'-diaminodiphenylether (3,4'-ODA) with terephthaloyl chloride (TCl). This relatively simple process uses only one amide solvent, and therefore spinning can be done directly after the polymer production.

Aramid fiber characteristics

Aramids share a high degree of orientation with other fibers such as

ultra-high-molecular-weight polyethylene Ultra-high-molecular-weight polyethylene (UHMWPE, UHMW) is a subset of the thermoplastic polyethylene. Also known as high-modulus polyethylene, (HMPE), it has extremely long chains, with a molecular mass usually between 3.5 and 7.5 million amu. T ...

, a characteristic that dominates their properties.

General

* good resistance to abrasion * good resistance to organic solvents * nonconductive * very high

melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends ...

(>500 °C) * low flammability * good fabric integrity at elevated

temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...

s * sensitive to acids and salts * sensitive to

ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...

radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes: * ''electromagnetic radiation'', such as radio waves, microwaves, infrared, visi ...

* prone to electrostatic charge build-up unless finished

Para-aramids

* para-aramid fibers, such as Kevlar and Twaron, provide outstanding strength-to-weight properties * high chord modulus * high tenacity * low creep * low elongation at break (~3.5%) * difficult to dye – usually solution-dyed

Uses

* flame-resistant clothing * heat-protective clothing and

helmet A helmet is a form of protective gear worn to protect the head. More specifically, a helmet complements the skull in protecting the human brain. Ceremonial or symbolic helmets (e.g., a policeman's helmet in the United Kingdom) without protect ...

s *

, competing with

polyethylene Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging ( plastic bags, plastic films, geomembranes and containers including bo ...

-based fiber products such as

Dyneema Ultra-high-molecular-weight polyethylene (UHMWPE, UHMW) is a subset of the thermoplastic polyethylene. Also known as high-modulus polyethylene, (HMPE), it has extremely long chains, with a molecular mass usually between 3.5 and 7.5 million amu. T ...

and Spectra *

composite material A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...

s *

replacement (e.g.

brake lining Brake linings are the consumable surfaces in brake systems, such as drum brakes and disc brakes used in transport vehicles. History Brake linings were invented by Bertha Benz (the wife of Karl Benz, who invented the first patented automobile) du ...

s) * hot air

filtration Filtration is a physical separation process that separates solid matter and fluid from a mixture using a ''filter medium'' that has a complex structure through which only the fluid can pass. Solid particles that cannot pass through the filter ...

s *

tire A tire (American English) or tyre (British English) is a ring-shaped component that surrounds a Rim (wheel), wheel's rim to transfer a vehicle's load from the axle through the wheel to the ground and to provide Traction (engineering), t ...

s, newly as Sulfron (sulfur-modified

) * mechanical

rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, and ...

goods reinforcement *

rope A rope is a group of yarns, plies, fibres, or strands that are twisted or braided together into a larger and stronger form. Ropes have tensile strength and so can be used for dragging and lifting. Rope is thicker and stronger than similarly ...

s and

cables Cable may refer to: Mechanical * Nautical cable, an assembly of three or more ropes woven against the weave of the ropes, rendering it virtually waterproof * Wire rope, a type of rope that consists of several strands of metal wire laid into a hel ...

* V-belts (automotive, machinery, equipment, and more) * wicks for

fire dancing Fire performance is a group of performance arts or skills that involve the manipulation of fire Fire is the rapid oxidation of a material (the fuel) in the exothermic chemical process of combustion, releasing heat, light, and various ...

optical fiber cable A fiber-optic cable, also known as an optical-fiber cable, is an assembly similar to an electrical cable, but containing one or more optical fibers that are used to carry light. The optical fiber elements are typically individually coated with ...

systems *

sail cloth A sail is a tensile structure—which is made from fabric or other membrane materials—that uses wind power to propel sailing craft, including sailing ships, sailboats, windsurfers, ice boats, and even sail-powered land vehicles. Sails may ...

(not necessarily racing

boat A boat is a watercraft of a large range of types and sizes, but generally smaller than a ship, which is distinguished by its larger size, shape, cargo or passenger capacity, or its ability to carry boats. Small boats are typically found on inl ...

sails) *

sport Sport pertains to any form of Competition, competitive physical activity or game that aims to use, maintain, or improve physical ability and Skill, skills while providing enjoyment to participants and, in some cases, entertainment to specta ...

ing goods *

drum The drum is a member of the percussion group of musical instruments. In the Hornbostel-Sachs classification system, it is a membranophone. Drums consist of at least one membrane, called a drumhead or drum skin, that is stretched over a she ...

heads * wind instrument

reed Reed or Reeds may refer to: Science, technology, biology, and medicine * Reed bird (disambiguation) * Reed pen, writing implement in use since ancient times * Reed (plant), one of several tall, grass-like wetland plants of the order Poales * ...

s, such as the Fibracell brand *

loudspeaker A loudspeaker (commonly referred to as a speaker or speaker driver) is an electroacoustic transducer that converts an electrical audio signal into a corresponding sound. A ''speaker system'', also often simply referred to as a "speaker" or " ...

diaphragms * boathull material *

fiber-reinforced concrete Fiber-reinforced concrete or fibre-reinforced concrete (FRC) is concrete containing fibrous material which increases its structural integrity. It contains short discrete fibers that are uniformly distributed and randomly oriented. Fibers inclu ...

reinforced thermoplastic pipe Reinforced thermoplastic pipe (RTP) is a type of pipe reinforced using a high strength synthetic fibre such as glass, aramid or carbon. It was initially developed in the early 1990s by Wavin Repox, Akzo Nobel and by Tubes d'Aquitaine from France, w ...

s * tennis strings, e.g. by Ashaway and Prince tennis companies *

hockey stick A hockey stick is a piece of sports equipment used by the players in all the forms of hockey to move the ball or puck (as appropriate to the type of hockey) either to push, pull, hit, strike, flick, steer, launch or stop the ball/ puck during pla ...

s (normally in composition with such materials as wood and carbon) *

snowboard Snowboards are boards where the user places both feet, usually secured, to the same board. The board itself is wider than most skis, with the ability to glide on snow."snowboarding." Dictionary.com Unabridged (v 1.1). Random House, Inc. 17 Mar ...

s *

jet engine A jet engine is a type of reaction engine discharging a fast-moving jet of heated gas (usually air) that generates thrust by jet propulsion. While this broad definition can include rocket, Pump-jet, water jet, and hybrid propulsion, the term ...

enclosures *

fishing reel A fishing reel is a hand- cranked reel used in angling to wind and stow fishing line, typical mounted onto a fishing rod, but may also be used to retrieve a tethered arrow when bowfishing. Modern recreational fishing reels usually have fittings ...

drag systems *

asphalt Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...

reinforcement *

Prusik A Prusik ( ) is a friction hitch or knot used to attach a loop of cord around a rope, applied in climbing, canyoneering, mountaineering, caving, rope rescue, ziplining, and by arborists. The term Prusik is a name for both the loops of cord used ...

s for rock climbers (which slide along the main rope and can otherwise melt due to friction).